| 1. Round | 19/08/2024 | Real Valladolid | - | Espanyol Barcelona | 1:0 | ||||
| 2. Round | 24/08/2024 | Espanyol Barcelona | - | Real Sociedad | 0:1 | ||||
| 3. Round | 28/08/2024 | Atlético Madrid | - | Espanyol Barcelona | 0:0 | ||||
| 4. Round | 31/08/2024 | Espanyol Barcelona | - | Rayo Vallecano | 2:1 | ||||
| 5. Round | 14/09/2024 | Espanyol Barcelona | - | CD Alavés | 3:2 | ||||
| 6. Round | 21/09/2024 | Real Madrid | - | Espanyol Barcelona | 4:1 | ||||
| 7. Round | 26/09/2024 | Espanyol Barcelona | - | Villarreal CF | 1:2 | ||||
| 8. Round | 29/09/2024 | Real Betis | - | Espanyol Barcelona | 1:0 | ||||
| 9. Round | 05/10/2024 | Espanyol Barcelona | - | RCD Mallorca | 2:1 | ||||
| 10. Round | 19/10/2024 | Athletic Club | - | Espanyol Barcelona | 4:1 |
Spain