| 2. Round | 12/09/1965 | RCD Mallorca | - | UD Las Palmas | 4:1 |  |
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| 3. Round | 19/09/1965 | UD Las Palmas | - | Real Zaragoza | 2:1 | ||||
| 4. Round | 26/09/1965 | UD Las Palmas | - | CE Sabadell | 1:0 | ||||
| 5. Round | 03/10/1965 | Elche CF | - | UD Las Palmas | 1:1 | ||||
| 6. Round | 10/10/1965 | Real Betis | - | UD Las Palmas | 1:0 | ||||
| 9. Round | 14/11/1965 | CD Málaga | - | UD Las Palmas | 1:0 |
Spain