| 4. Round | 25/10/2006 | CD Castellón | - | Villarreal CF | 0:2 | ||||
| Round of 16 | 10/01/2007 | Real Valladolid | - | Villarreal CF | 2:1 |  |
 |
| 4. Round | 25/10/2006 | CD Castellón | - | Villarreal CF | 0:2 | ||||
| Round of 16 | 10/01/2007 | Real Valladolid | - | Villarreal CF | 2:1 | |
|
| José María Romero Poyón | |
| Born: | 10.12.1978 |
| Place of birth: |
Sevilla, 
Spain |
| Nationality: |
Spain
|
| Height: | 185 cm |
| Weight: | 74 kg |
| Position(s): | Right Winger Left Winger |
| Foot: | right |