| #1 | 05/05/1965 | Ireland | - | Spain | 1:0 | ||||
| #2 | 08/05/1965 | Scotland | - | Spain | 0:0 | ||||
| #3 | 27/10/1965 | Spain | - | Ireland | 4:1 | ||||
| #4 | 10/11/1965 | Spain | - | Ireland | 1:0 |  |
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| #5 | 08/12/1965 | Spain | - | England | 0:2 | ||||
| #6 | 23/06/1966 | Spain | - | Uruguay | 1:1 | ||||
| #7 | 13/07/1966 | Argentina | - | Spain | 2:1 | ||||
| #8 | 31/05/1967 | Spain | - | Turkey | 2:0 | ||||
| #9 | 17/10/1968 | France | - | Spain | 1:3 | |
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| #10 | 27/10/1968 | Yugoslavia | - | Spain | 0:0 | ||||
| #11 | 26/03/1969 | Spain | - | Switzerland | 1:0 | ||||
| #12 | 11/02/1970 | Spain | - | Germany | 2:0 | ||||
| #13 | 12/04/1972 | Greece | - | Spain | 0:0 | ||||
| #14 | 23/05/1972 | Spain | - | Uruguay | 2:0 | ||||
| #15 | 11/10/1972 | Spain | - | Argentina | 1:0 | ||||
| #16 | 19/10/1972 | Spain | - | Yugoslavia | 2:2 |
Spain