| 2. Round | 10/09/1993 | Albacete | - | FC Barcelona | 0:0 | ||||
| 3. Round | 18/09/1993 | Athletic Club | - | FC Barcelona | 0:0 | ||||
| 5. Round | 03/10/1993 | CA Osasuna | - | FC Barcelona | 2:3 | ||||
| 7. Round | 16/10/1993 | Deportivo La Coruña | - | FC Barcelona | 1:0 | ||||
| 8. Round | 24/10/1993 | FC Barcelona | - | Real Oviedo | 1:0 | ||||
| 9. Round | 29/10/1993 | Atlético Madrid | - | FC Barcelona | 4:3 |  |
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| 11. Round | 09/11/1993 | CD Tenerife | - | FC Barcelona | 2:3 | ||||
| 23. Round | 12/02/1994 | Real Zaragoza | - | FC Barcelona | 6:3 | ||||
| 36. Round | 30/04/1994 | FC Barcelona | - | Sporting Gijón | 4:0 |
Spain