| Group F | 14/09/2021 | Villarreal CF | - | Atalanta | 2:2 | ||||
| Group F | 29/09/2021 | Manchester United | - | Villarreal CF | 2:1 | ||||
| Group F | 20/10/2021 | BSC Young Boys | - | Villarreal CF | 1:4 | ||||
| Group F | 23/11/2021 | Villarreal CF | - | Manchester United | 0:2 | ||||
| Group F | 09/12/2021 | Atalanta | - | Villarreal CF | 2:3 | ||||
| Round of 16 | 22/02/2022 | Villarreal CF | - | Juventus | 1:1 | ||||
| Quarter-finals | 06/04/2022 | Villarreal CF | - | Bayern München | 1:0 | ||||
| Quarter-finals | 12/04/2022 | Bayern München | - | Villarreal CF | 1:1 |  |
|||
| Semi-finals | 27/04/2022 | Liverpool FC | - | Villarreal CF | 2:0 | ||||
| Semi-finals | 03/05/2022 | Villarreal CF | - | Liverpool FC | 2:3 |
Argentina
Spain 