| Group I | 22/10/2020 | Villarreal CF | - | Sivasspor | 5:3 |  |
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| Group I | 29/10/2020 | Qarabağ FK | - | Villarreal CF | 1:3 | ||||
| Group I | 26/11/2020 | Maccabi Tel Aviv | - | Villarreal CF | 1:1 | ||||
| Group I | 03/12/2020 | Sivasspor | - | Villarreal CF | 0:1 | ||||
| Round of 32 | 18/02/2021 | RB Salzburg | - | Villarreal CF | 0:2 | ||||
| Round of 32 | 25/02/2021 | Villarreal CF | - | RB Salzburg | 2:1 | ||||
| Round of 16 | 11/03/2021 | Dinamo Kiev | - | Villarreal CF | 0:2 | ||||
| Round of 16 | 18/03/2021 | Villarreal CF | - | Dinamo Kiev | 2:0 | ||||
| Quarter-finals | 08/04/2021 | Dinamo Zagreb | - | Villarreal CF | 0:1 | ||||
| Quarter-finals | 15/04/2021 | Villarreal CF | - | Dinamo Zagreb | 2:1 | ||||
| Semi-finals | 29/04/2021 | Villarreal CF | - | Arsenal FC | 2:1 | ||||
| Final | 26/05/2021 | Villarreal CF | - | Manchester United | 11:10 pso | |
Argentina
Spain 