| 1. Round | 13/09/1969 | UD Las Palmas | - | Elche CF | 5:1 | ||||
| 2. Round | 21/09/1969 | Elche CF | - | Real Madrid | 0:2 | ||||
| 3. Round | 28/09/1969 | Deportivo La Coruña | - | Elche CF | 1:0 | ||||
| 4. Round | 05/10/1969 | Elche CF | - | Pontevedra CF | 1:0 | ||||
| 5. Round | 12/10/1969 | Athletic Club | - | Elche CF | 2:0 | ||||
| 6. Round | 19/10/1969 | Elche CF | - | Real Sociedad | 4:2 |  |
|||
| 7. Round | 26/10/1969 | CE Sabadell | - | Elche CF | 1:2 | ||||
| 8. Round | 02/11/1969 | Elche CF | - | Sevilla FC | 5:0 | ||||
| 9. Round | 09/11/1969 | Atlético Madrid | - | Elche CF | 4:1 | ||||
| 12. Round | 30/11/1969 | Elche CF | - | RCD Mallorca | 1:1 | ||||
| 14. Round | 14/12/1969 | Elche CF | - | Real Zaragoza | 1:1 | ||||
| 18. Round | 11/01/1970 | Elche CF | - | Deportivo La Coruña | 1:0 | ||||
| 19. Round | 18/01/1970 | Pontevedra CF | - | Elche CF | 1:1 | ||||
| 20. Round | 25/01/1970 | Elche CF | - | Athletic Club | 0:1 | ||||
| 27. Round | 29/03/1970 | RCD Mallorca | - | Elche CF | 0:0 | ||||
| 28. Round | 05/04/1970 | Elche CF | - | Granada CF | 1:0 | |
|||
| 29. Round | 12/04/1970 | Real Zaragoza | - | Elche CF | 3:2 | ||||
| 30. Round | 19/04/1970 | Elche CF | - | FC Barcelona | 1:0 |
Paraguay