| 6. Round | 12/10/1980 | Real Valladolid | - | Espanyol Barcelona | 3:1 | ||||
| 7. Round | 19/10/1980 | Sporting Gijón | - | Real Valladolid | 4:1 | ||||
| 12. Round | 22/11/1980 | Real Valladolid | - | Real Betis | 2:1 | ||||
| 14. Round | 06/12/1980 | Real Valladolid | - | FC Barcelona | 1:1 | ||||
| 15. Round | 13/12/1980 | UD Salamanca | - | Real Valladolid | 2:1 | ||||
| 16. Round | 20/12/1980 | Real Valladolid | - | Real Zaragoza | 1:1 |  |
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| 18. Round | 03/01/1981 | Real Valladolid | - | Atlético Madrid | 0:2 | ||||
| 20. Round | 17/01/1981 | Real Valladolid | - | Athletic Club | 0:0 |
Spain