| 10. Round | 02/11/1990 | Sevilla FC | - | Sporting Gijón | 1:0 | ||||
| 13. Round | 01/12/1990 | Sporting Gijón | - | Cádiz CF | 3:1 |  |
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| 14. Round | 08/12/1990 | Real Sociedad | - | Sporting Gijón | 1:0 | ||||
| 15. Round | 15/12/1990 | Sporting Gijón | - | CD Logroñés | 1:0 | ||||
| 16. Round | 29/12/1990 | Real Oviedo | - | Sporting Gijón | 0:0 | |
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| 19. Round | 19/01/1991 | Sporting Gijón | - | Valencia CF | 1:1 | ||||
| 20. Round | 26/01/1991 | Sporting Gijón | - | Real Betis | 4:0 |  |
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| 21. Round | 02/02/1991 | Real Valladolid | - | Sporting Gijón | 0:0 | |
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| 22. Round | 09/02/1991 | Sporting Gijón | - | CD Tenerife | 2:1 | ||||
| 23. Round | 23/02/1991 | Athletic Club | - | Sporting Gijón | 1:2 | ||||
| 24. Round | 02/03/1991 | Sporting Gijón | - | CA Osasuna | 1:1 | ||||
| 25. Round | 09/03/1991 | Real Burgos | - | Sporting Gijón | 1:1 | ||||
| 26. Round | 16/03/1991 | Atlético Madrid | - | Sporting Gijón | 3:1 | ||||
| 30. Round | 13/04/1991 | RCD Mallorca | - | Sporting Gijón | 1:1 | ||||
| 32. Round | 27/04/1991 | Cádiz CF | - | Sporting Gijón | 1:1 | ||||
| 34. Round | 10/05/1991 | CD Logroñés | - | Sporting Gijón | 1:2 | ||||
| 35. Round | 18/05/1991 | Sporting Gijón | - | Real Oviedo | 0:0 | |
Spain