| 22. Round | 19/02/2023 | Atlético Madrid | - | Athletic Club | 1:0 | ||||
| 23. Round | 26/02/2023 | Athletic Club | - | Girona FC | 2:3 | ||||
| 24. Round | 05/03/2023 | Rayo Vallecano | - | Athletic Club | 0:0 | ||||
| 25. Round | 12/03/2023 | Athletic Club | - | FC Barcelona | 0:1 | ||||
| 26. Round | 17/03/2023 | Real Valladolid | - | Athletic Club | 1:3 | ||||
| 27. Round | 01/04/2023 | Athletic Club | - | Getafe CF | 0:0 | ||||
| 32. Round | 01/05/2023 | RCD Mallorca | - | Athletic Club | 1:1 | ||||
| 36. Round | 25/05/2023 | CA Osasuna | - | Athletic Club | 2:0 |
Spain