| 3. Round | 28/08/2024 | Athletic Club | - | Valencia CF | 1:0 | ||||
| 4. Round | 31/08/2024 | Athletic Club | - | Atlético Madrid | 0:1 | ||||
| 5. Round | 15/09/2024 | UD Las Palmas | - | Athletic Club | 2:3 | ||||
| 7. Round | 19/09/2024 | CD Leganés | - | Athletic Club | 0:2 | ||||
| 6. Round | 22/09/2024 | Athletic Club | - | RC Celta | 3:1 | ||||
| 8. Round | 29/09/2024 | Athletic Club | - | Sevilla FC | 1:1 |  |
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| 10. Round | 19/10/2024 | Athletic Club | - | Espanyol Barcelona | 4:1 | ||||
| 11. Round | 28/10/2024 | RCD Mallorca | - | Athletic Club | 0:0 | ||||
| 12. Round | 03/11/2024 | Athletic Club | - | Real Betis | 1:1 | ||||
| 13. Round | 10/11/2024 | Real Valladolid | - | Athletic Club | 1:1 | ||||
| 14. Round | 24/11/2024 | Athletic Club | - | Real Sociedad | 1:0 | ||||
| 15. Round | 01/12/2024 | Rayo Vallecano | - | Athletic Club | 1:2 | ||||
| 19. Round | 04/12/2024 | Athletic Club | - | Real Madrid | 2:1 |  |
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| 16. Round | 08/12/2024 | Athletic Club | - | Villarreal CF | 2:0 |
Spain