| 8. Round | 20/10/1985 | Cádiz CF | - | Hércules CF | 2:0 | ||||
| 9. Round | 27/10/1985 | Hércules CF | - | Real Valladolid | 1:0 | ||||
| 10. Round | 01/11/1985 | Real Madrid | - | Hércules CF | 4:0 | ||||
| 11. Round | 09/11/1985 | Hércules CF | - | RC Celta | 5:2 | ||||
| 14. Round | 30/11/1985 | Real Betis | - | Hércules CF | 1:0 | ||||
| 15. Round | 07/12/1985 | Hércules CF | - | Valencia CF | 3:2 | ||||
| 16. Round | 14/12/1985 | Espanyol Barcelona | - | Hércules CF | 4:1 | ||||
| 28. Round | 08/03/1986 | RC Celta | - | Hércules CF | 1:2 | ||||
| 30. Round | 22/03/1986 | Real Sociedad | - | Hércules CF | 6:0 |  |
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| 31. Round | 29/03/1986 | Hércules CF | - | Real Betis | 2:3 | ||||
| 32. Round | 05/04/1986 | Valencia CF | - | Hércules CF | 3:1 | ||||
| 33. Round | 12/04/1986 | Hércules CF | - | Espanyol Barcelona | 1:1 |  |
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| 34. Round | 19/04/1986 | Racing Santander | - | Hércules CF | 4:1 |
Spain