| 1. Round | 09/11/1999 | Real Unión | - | Real Valladolid | 1:1 |  |
 |
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| 1. Round | 01/12/1999 | Real Valladolid | - | Real Unión | 0:1 | |
| 1. Round | 09/11/1999 | Real Unión | - | Real Valladolid | 1:1 | |
|
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| 1. Round | 01/12/1999 | Real Valladolid | - | Real Unión | 0:1 | |
| Santiago Labiano Herrera | |
| Born: | 12.03.1974 |
| Place of birth: |
Pamplona, 
Spain |
| Nationality: |
Spain
|
| Height: | 180 cm |
| Weight: | 75 kg |