| 19. Round | 11/02/2023 | CD Alavés [Women] | - | FC Barcelona [Women] | 0:4 |  |
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| 20. Round | 04/03/2023 | Madrid CFF [Women] | - | CD Alavés [Women] | 5:1 | |
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| 21. Round | 11/03/2023 | CD Alavés [Women] | - | Sporting de Huelva [Women] | 2:1 | |
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| 22. Round | 19/03/2023 | Real Sociedad [Women] | - | CD Alavés [Women] | 6:5 | ||||
| 23. Round | 26/03/2023 | CD Alavés [Women] | - | Atlético Madrid [Women] | 1:2 | |
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| 24. Round | 01/04/2023 | Sevilla FC [Women] | - | CD Alavés [Women] | 4:2 | ||||
| 25. Round | 15/04/2023 | Athletic Club [Women] | - | CD Alavés [Women] | 1:0 | ||||
| 26. Round | 22/04/2023 | CD Alavés [Women] | - | Levante Las Planas [Women] | 1:0 | |
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| 28. Round | 06/05/2023 | CD Alavés [Women] | - | UDG Tenerife Sur [Women] | 1:1 | ||||
| 29. Round | 13/05/2023 | Real Betis [Women] | - | CD Alavés [Women] | 1:1 | |
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| 30. Round | 20/05/2023 | CD Alavés [Women] | - | Alhama CF [Women] | 1:1 |
Spain