| 2. Round | 27/08/1999 | Real Sociedad | - | Atlético Madrid | 4:1 | ||||
| 3. Round | 11/09/1999 | Atlético Madrid | - | RC Celta | 1:2 | ||||
| 18. Round | 04/01/2000 | Sevilla FC | - | Atlético Madrid | 2:1 |  |
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| 27. Round | 04/03/2000 | Atlético Madrid | - | Real Betis | 0:0 | ||||
| 28. Round | 11/03/2000 | Real Valladolid | - | Atlético Madrid | 1:0 | ||||
| 30. Round | 24/03/2000 | CD Numancia | - | Atlético Madrid | 3:0 | ||||
| 31. Round | 01/04/2000 | Atlético Madrid | - | Athletic Club | 1:2 |
Spain