| 1. Round | 23/09/1945 | FC Barcelona | - | Sporting Gijón | 2:0 | ||||
| 2. Round | 30/09/1945 | Sporting Gijón | - | Hércules CF | 2:0 | ||||
| 3. Round | 07/10/1945 | RC Celta | - | Sporting Gijón | 2:3 | ||||
| 4. Round | 14/10/1945 | Sporting Gijón | - | CD Castellón | 2:0 | ||||
| 5. Round | 21/10/1945 | Sevilla FC | - | Sporting Gijón | 3:2 | ||||
| 6. Round | 28/10/1945 | Sporting Gijón | - | Real Madrid | 1:1 | ||||
| 11. Round | 09/12/1945 | Sporting Gijón | - | Valencia CF | 1:2 | ||||
| 16. Round | 20/01/1946 | Sporting Gijón | - | RC Celta | 2:1 | ||||
| 23. Round | 10/03/1946 | Sporting Gijón | - | Athletic Club | 0:0 | ||||
| 24. Round | 17/03/1946 | Valencia CF | - | Sporting Gijón | 1:1 |
Spain