| 2. Round | 17/09/2022 | Real Madrid [Women] | - | Valencia CF [Women] | 2:0 | ||||
| 5. Round | 16/10/2022 | Real Madrid [Women] | - | CD Alavés [Women] | 7:1 | ||||
| 6. Round | 23/10/2022 | Levante UD [Women] | - | Real Madrid [Women] | 2:2 | ||||
| 7. Round | 30/10/2022 | Real Madrid [Women] | - | Sevilla FC [Women] | 2:0 | ||||
| 8. Round | 06/11/2022 | Real Madrid [Women] | - | FC Barcelona [Women] | 0:4 | ||||
| 10. Round | 26/11/2022 | Real Madrid [Women] | - | Alhama CF [Women] | 5:1 | ||||
| 11. Round | 03/12/2022 | Levante Las Planas [Women] | - | Real Madrid [Women] | 1:4 | ||||
| 16. Round | 25/01/2023 | CD Alavés [Women] | - | Real Madrid [Women] | 1:3 | ||||
| 20. Round | 04/03/2023 | Alhama CF [Women] | - | Real Madrid [Women] | 1:5 | ||||
| 27. Round | 30/04/2023 | Real Madrid [Women] | - | Madrid CFF [Women] | 3:2 | ||||
| 30. Round | 19/05/2023 | Real Sociedad [Women] | - | Real Madrid [Women] | 1:1 |
Spain