5. Round | 16/10/2022 | Villarreal CF [Women] | - | Sevilla FC [Women] | 0:5 | ||||
1. Round | 03/11/2022 | Villarreal CF [Women] | - | Real Madrid [Women] | 0:4 | ||||
8. Round | 06/11/2022 | Villarreal CF [Women] | - | Real Betis [Women] | 0:3 | ||||
10. Round | 26/11/2022 | Villarreal CF [Women] | - | Athletic Bilbao [Women] | 1:6 | ||||
14. Round | 07/01/2023 | Villarreal CF [Women] | - | Levante UD [Women] | 0:6 | ||||
16. Round | 24/01/2023 | Valencia CF [Women] | - | Villarreal CF [Women] | 2:0 |