| 1. Round | 26/08/2007 | Espanyol Barcelona | - | Real Valladolid | 0:1 | ||||
| 2. Round | 02/09/2007 | Real Valladolid | - | Deportivo La Coruña | 2:2 | ||||
| 3. Round | 15/09/2007 | Valencia CF | - | Real Valladolid | 2:1 | ||||
| 4. Round | 23/09/2007 | Real Valladolid | - | Real Madrid | 1:1 |  |
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| 5. Round | 26/09/2007 | RCD Mallorca | - | Real Valladolid | 4:2 | ||||
| 6. Round | 30/09/2007 | Real Valladolid | - | Real Murcia | 1:4 |  |
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| 8. Round | 21/10/2007 | Real Valladolid | - | Athletic Club | 1:2 | ||||
| 13. Round | 25/11/2007 | Atlético Madrid | - | Real Valladolid | 4:3 |
France