| 2. Round | 07/09/1991 | Sporting Gijón | - | Athletic Club | 3:2 | ||||
| 4. Round | 28/09/1991 | CD Logroñés | - | Athletic Club | 0:1 |  |
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| 5. Round | 06/10/1991 | Athletic Club | - | Deportivo La Coruña | 0:0 | ||||
| 6. Round | 20/10/1991 | Albacete | - | Athletic Club | 4:0 |  |
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| 10. Round | 15/11/1991 | Real Sociedad | - | Athletic Club | 2:0 | ||||
| 11. Round | 23/11/1991 | Athletic Club | - | Real Zaragoza | 1:0 | ||||
| 15. Round | 20/12/1991 | Athletic Club | - | Valencia CF | 2:3 | |
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| 17. Round | 11/01/1992 | Athletic Club | - | Cádiz CF | 3:1 | ||||
| 24. Round | 29/02/1992 | Deportivo La Coruña | - | Athletic Club | 0:0 | ||||
| 32. Round | 25/04/1992 | Atlético Madrid | - | Athletic Club | 3:1 | ||||
| 33. Round | 02/05/1992 | Athletic Club | - | CA Osasuna | 2:1 | ||||
| 34. Round | 08/05/1992 | Valencia CF | - | Athletic Club | 3:1 | ||||
| 35. Round | 16/05/1992 | Athletic Club | - | CD Tenerife | 3:1 | ||||
| 38. Round | 06/06/1992 | FC Barcelona | - | Athletic Club | 2:0 |
Spain