| 1. Round | 11/09/1960 | Espanyol Barcelona | - | Valencia CF | 3:0 | ||||
| 2. Round | 17/09/1960 | Valencia CF | - | Athletic Club | 1:0 | ||||
| 5. Round | 08/10/1960 | Valencia CF | - | Real Madrid | 0:1 | ||||
| 6. Round | 16/10/1960 | Real Zaragoza | - | Valencia CF | 1:1 | ||||
| 9. Round | 13/11/1960 | Valencia CF | - | FC Barcelona | 0:2 | ||||
| 12. Round | 04/12/1960 | Racing Santander | - | Valencia CF | 3:0 | ||||
| 14. Round | 18/12/1960 | Real Sociedad | - | Valencia CF | 1:1 | ||||
| 15. Round | 01/01/1961 | Valencia CF | - | Elche CF | 0:0 | ||||
| 17. Round | 15/01/1961 | Athletic Club | - | Valencia CF | 4:1 | ||||
| 19. Round | 29/01/1961 | Valencia CF | - | Granada CF | 3:1 | ||||
| 20. Round | 04/02/1961 | Real Madrid | - | Valencia CF | 2:0 | ||||
| 28. Round | 09/04/1961 | Atlético Madrid | - | Valencia CF | 2:2 | ||||
| 30. Round | 30/04/1961 | Elche CF | - | Valencia CF | 4:1 |
Spain