| 1. Round | 03/09/1972 | Atlético Madrid | - | Valencia CF | 1:3 |  |
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| 2. Round | 09/09/1972 | Valencia CF | - | FC Barcelona | 0:1 | ||||
| 8. Round | 29/10/1972 | Real Betis | - | Valencia CF | 0:0 | ||||
| 9. Round | 04/11/1972 | Valencia CF | - | Real Madrid | 0:1 | ||||
| 10. Round | 11/11/1972 | Espanyol Barcelona | - | Valencia CF | 3:0 | |
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| 11. Round | 18/11/1972 | Valencia CF | - | Athletic Club | 4:1 | ||||
| 31. Round | 28/04/1973 | Valencia CF | - | RC Celta | 1:0 |
Spain