| 1. Round | 30/08/1985 | Real Sociedad | - | RC Celta | 1:1 | ||||
| 2. Round | 03/09/1985 | RC Celta | - | Real Betis | 0:1 | ||||
| 3. Round | 07/09/1985 | Valencia CF | - | RC Celta | 3:1 |  |
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| 4. Round | 14/09/1985 | RC Celta | - | Espanyol Barcelona | 2:1 | ||||
| 5. Round | 28/09/1985 | Racing Santander | - | RC Celta | 3:0 | |
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| 6. Round | 06/10/1985 | RC Celta | - | Real Zaragoza | 1:2 | ||||
| 7. Round | 13/10/1985 | Atlético Madrid | - | RC Celta | 3:1 | ||||
| 8. Round | 19/10/1985 | RC Celta | - | CA Osasuna | 2:0 | ||||
| 9. Round | 27/10/1985 | Athletic Club | - | RC Celta | 3:1 | ||||
| 10. Round | 02/11/1985 | RC Celta | - | Sevilla FC | 1:2 | ||||
| 13. Round | 23/11/1985 | Cádiz CF | - | RC Celta | 1:0 | ||||
| 14. Round | 30/11/1985 | RC Celta | - | Real Valladolid | 3:2 |  |
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| 15. Round | 06/12/1985 | Real Madrid | - | RC Celta | 4:0 | ||||
| 16. Round | 14/12/1985 | UD Las Palmas | - | RC Celta | 1:1 | ||||
| 17. Round | 21/12/1985 | RC Celta | - | Sporting Gijón | 1:1 | |
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| 18. Round | 28/12/1985 | RC Celta | - | Real Sociedad | 1:3 | |
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| 20. Round | 11/01/1986 | RC Celta | - | Valencia CF | 1:0 | ||||
| 22. Round | 25/01/1986 | RC Celta | - | Racing Santander | 1:2 | ||||
| 24. Round | 08/02/1986 | RC Celta | - | Atlético Madrid | 0:1 | ||||
| 25. Round | 15/02/1986 | CA Osasuna | - | RC Celta | 2:1 |
Spain