| 3. Round | 01/11/2020 | CF La Nucía | - | Villarreal CF B | 1:2 | ||||
| 5. Round | 21/11/2020 | Atzeneta UE | - | Villarreal CF B | 1:1 | ||||
| 4. Round | 25/11/2020 | Villarreal CF B | - | CD Alcoyano | 3:0 | ||||
| 7. Round | 06/12/2020 | Hércules CF | - | Villarreal CF B | 0:0 | ||||
| 11. Round | 24/01/2021 | Levante UD B | - | Villarreal CF B | 0:0 | ||||
| 17. Round | 14/03/2021 | Orihuela CF | - | Villarreal CF B | 2:4 |  |
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| 18. Round | 21/03/2021 | Villarreal CF B | - | UD Ibiza | 0:3 |
Spain