| #1 | 23/11/1961 | Spain | - | Morocco | 3:2 |  |
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| #2 | 11/03/1964 | Spain | - | Ireland | 5:1 | |
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| #3 | 08/04/1964 | Ireland | - | Spain | 0:2 | ||||
| #4 | 17/06/1964 | Spain | - | Hungary | 2:1 aet | ||||
| #5 | 21/06/1964 | Spain | - | USSR | 2:1 | |
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| #6 | 15/11/1964 | Portugal | - | Spain | 2:1 | ||||
| #7 | 05/05/1965 | Ireland | - | Spain | 1:0 | ||||
| #8 | 08/05/1965 | Scotland | - | Spain | 0:0 | ||||
| #9 | 27/10/1965 | Spain | - | Ireland | 4:1 | ||||
| #10 | 10/11/1965 | Spain | - | Ireland | 1:0 | ||||
| #11 | 08/12/1965 | Spain | - | England | 0:2 | ||||
| #12 | 23/06/1966 | Spain | - | Uruguay | 1:1 | ||||
| #13 | 20/07/1966 | Germany | - | Spain | 2:1 | ||||
| #14 | 01/10/1967 | CSSR | - | Spain | 1:0 |
Spain