| 18. Round | 04/02/2023 | Valencia CF [Women] | - | Real Madrid [Women] | 1:6 | ||||
| 20. Round | 04/03/2023 | Valencia CF [Women] | - | UDG Tenerife Sur [Women] | 2:1 | ||||
| 21. Round | 12/03/2023 | Athletic Club [Women] | - | Valencia CF [Women] | 0:2 |  |
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| 22. Round | 17/03/2023 | FC Barcelona [Women] | - | Valencia CF [Women] | 5:1 |  |
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| 23. Round | 26/03/2023 | Valencia CF [Women] | - | Alhama CF [Women] | 1:3 | ||||
| 26. Round | 22/04/2023 | Real Sociedad [Women] | - | Valencia CF [Women] | 4:0 | ||||
| 27. Round | 29/04/2023 | Valencia CF [Women] | - | CD Alavés [Women] | 2:1 | ||||
| 28. Round | 07/05/2023 | Levante UD [Women] | - | Valencia CF [Women] | 1:1 | |
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| 29. Round | 14/05/2023 | Valencia CF [Women] | - | Madrid CFF [Women] | 0:2 | ||||
| 30. Round | 19/05/2023 | Sevilla FC [Women] | - | Valencia CF [Women] | 2:0 |
Spain