| 3. Round | 22/11/2022 | Espanyol Barcelona [Women] | - | Villarreal CF [Women] | 1:2 aet |  |
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| Round of 16 | 10/01/2023 | Villarreal CF [Women] | - | Sevilla FC [Women] | annull. | ||||
| Quarter-finals | 09/03/2023 | Villarreal CF [Women] | - | Real Madrid [Women] | 1:2 aet | |
| 3. Round | 22/11/2022 | Espanyol Barcelona [Women] | - | Villarreal CF [Women] | 1:2 aet | |
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| Round of 16 | 10/01/2023 | Villarreal CF [Women] | - | Sevilla FC [Women] | annull. | ||||
| Quarter-finals | 09/03/2023 | Villarreal CF [Women] | - | Real Madrid [Women] | 1:2 aet | |
| María Llompart Pons | |
| Born: | 19.10.2000 |
| Place of birth: |
Begues, 
Spain |
| Nationality: |
Spain
|
| Height: | 161 cm |
| Weight: | 55 kg |
| Position(s): | Central Midfielder |
| Foot: | right |