| Group D | 02/11/2005 | SL Benfica | - | Villarreal CF | 0:1 | ||||
| Group D | 22/11/2005 | Manchester United | - | Villarreal CF | 0:0 | ||||
| Semi-finals | 19/04/2006 | Arsenal FC | - | Villarreal CF | 1:0 | ||||
| Semi-finals | 25/04/2006 | Villarreal CF | - | Arsenal FC | 0:0 |
| Group D | 02/11/2005 | SL Benfica | - | Villarreal CF | 0:1 | ||||
| Group D | 22/11/2005 | Manchester United | - | Villarreal CF | 0:0 | ||||
| Semi-finals | 19/04/2006 | Arsenal FC | - | Villarreal CF | 1:0 | ||||
| Semi-finals | 25/04/2006 | Villarreal CF | - | Arsenal FC | 0:0 |
| Mariano Damián Barbosa | |
| Born: | 27.07.1984 |
| Place of birth: |
Lanús, 
Argentina |
| Nationality: |
Argentina
Italy |
| Height: | 188 cm |
| Weight: | 79 kg |
| Position(s): | Goalkeeper |
| Foot: | right |