| 4. Round | 29/09/2024 | Valencia CF [Women] | - | Sevilla FC [Women] | 1:3 | ||||
| 6. Round | 13/10/2024 | Valencia CF [Women] | - | Granada CF [Women] | 0:2 | ||||
| 13. Round | 15/12/2024 | Valencia CF [Women] | - | FC Barcelona [Women] | 0:1 | ||||
| 8. Round | 18/12/2024 | Valencia CF [Women] | - | Deportivo La Coruña [Women] | 0:2 | ||||
| 9. Round | 05/01/2025 | Levante UD [Women] | - | Valencia CF [Women] | 0:1 | ||||
| 17. Round | 01/02/2025 | Deportivo La Coruña [Women] | - | Valencia CF [Women] | 1:1 | ||||
| 27. Round | 27/04/2025 | Real Sociedad [Women] | - | Valencia CF [Women] | 0:2 | ||||
| 28. Round | 03/05/2025 | Valencia CF [Women] | - | SD Eibar [Women] | 2:0 |
Spain