| 3. Round | 07/09/1985 | Espanyol Barcelona | - | Real Madrid | 1:2 | ||||
| 4. Round | 14/09/1985 | Real Madrid | - | Racing Santander | 1:0 | ||||
| 8. Round | 20/10/1985 | Real Madrid | - | Athletic Club | 2:0 | ||||
| 12. Round | 16/11/1985 | Real Madrid | - | Cádiz CF | 3:1 | ||||
| 13. Round | 23/11/1985 | Real Valladolid | - | Real Madrid | 3:2 | ||||
| 15. Round | 06/12/1985 | Real Madrid | - | RC Celta | 4:0 | ||||
| 18. Round | 28/12/1985 | Real Madrid | - | Real Betis | 4:1 | ||||
| 19. Round | 04/01/1986 | Valencia CF | - | Real Madrid | 0:3 |  |
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| 20. Round | 11/01/1986 | Real Madrid | - | Espanyol Barcelona | 4:1 | ||||
| 23. Round | 01/02/1986 | Atlético Madrid | - | Real Madrid | 0:1 | ||||
| 26. Round | 22/02/1986 | Real Madrid | - | Sevilla FC | 2:1 | ||||
| 29. Round | 15/03/1986 | Cádiz CF | - | Real Madrid | 1:3 | |
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| 30. Round | 22/03/1986 | Real Madrid | - | Real Valladolid | 2:1 | ||||
| 31. Round | 28/03/1986 | UD Las Palmas | - | Real Madrid | 4:3 | ||||
| 32. Round | 05/04/1986 | RC Celta | - | Real Madrid | 1:5 | ||||
| 33. Round | 11/04/1986 | Real Madrid | - | Sporting Gijón | 2:1 | |
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| 34. Round | 19/04/1986 | Real Sociedad | - | Real Madrid | 5:3 |
Spain