| 4. Round | 19/10/1941 | Hércules CF | - | Real Oviedo | 4:1 | ||||
| 5. Round | 26/10/1941 | CD Castellón | - | Hércules CF | 4:0 | ||||
| 13. Round | 21/12/1941 | Hércules CF | - | Athletic Club | 3:1 | ||||
| 14. Round | 04/01/1942 | Hércules CF | - | FC Barcelona | 3:1 | ||||
| 15. Round | 11/01/1942 | Deportivo La Coruña | - | Hércules CF | 3:1 | ||||
| 16. Round | 18/01/1942 | Hércules CF | - | Sevilla FC | 1:0 | ||||
| 18. Round | 01/02/1942 | Hércules CF | - | CD Castellón | 0:1 | ||||
| 19. Round | 08/02/1942 | Atlético Aviación | - | Hércules CF | 5:1 | ||||
| 20. Round | 15/02/1942 | Espanyol Barcelona | - | Hércules CF | 2:0 | ||||
| 21. Round | 22/02/1942 | Hércules CF | - | RC Celta | 1:3 | ||||
| 23. Round | 08/03/1942 | Hércules CF | - | Valencia CF | 1:3 | ||||
| 24. Round | 22/03/1942 | Real Sociedad | - | Hércules CF | 2:1 | ||||
| 25. Round | 29/03/1942 | Hércules CF | - | Granada CF | 2:2 | ||||
| 26. Round | 05/04/1942 | Athletic Club | - | Hércules CF | 2:2 |
Spain