| 5. Round | 11/09/2022 | Real Madrid | - | RCD Mallorca | 4:1 |  |
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| 10. Round | 19/10/2022 | Real Sociedad | - | RCD Mallorca | 1:0 | ||||
| 11. Round | 22/10/2022 | Valencia CF | - | RCD Mallorca | 1:2 | ||||
| 13. Round | 06/11/2022 | Villarreal CF | - | RCD Mallorca | 0:2 | ||||
| 15. Round | 30/12/2022 | Getafe CF | - | RCD Mallorca | 2:0 | ||||
| 18. Round | 20/01/2023 | RCD Mallorca | - | RC Celta | 1:0 | ||||
| 20. Round | 05/02/2023 | RCD Mallorca | - | Real Madrid | 1:0 | ||||
| 21. Round | 11/02/2023 | Sevilla FC | - | RCD Mallorca | 2:0 | ||||
| 22. Round | 18/02/2023 | RCD Mallorca | - | Villarreal CF | 4:2 | |
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| 23. Round | 25/02/2023 | Espanyol Barcelona | - | RCD Mallorca | 2:1 | ||||
| 25. Round | 12/03/2023 | RCD Mallorca | - | Real Sociedad | 1:1 | ||||
| 26. Round | 19/03/2023 | Real Betis | - | RCD Mallorca | 1:0 | |
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| 27. Round | 31/03/2023 | RCD Mallorca | - | CA Osasuna | 0:0 | ||||
| 31. Round | 26/04/2023 | Atlético Madrid | - | RCD Mallorca | 3:1 |  |
Serbia
