| 1. Round | 01/12/1999 | CD Numancia | - | SD Compostela | 3:2 |  |
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| 2. Round | 15/12/1999 | CD Tenerife | - | SD Compostela | 2:2 | ||||
| 2. Round | 12/01/2000 | SD Compostela | - | CD Tenerife | 2:0 | ||||
| Round of 16 | 01/02/2000 | Villarreal CF | - | SD Compostela | 2:4 pso | |
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| Quarter-finals | 09/02/2000 | Espanyol Barcelona | - | SD Compostela | 5:1 | ||||
| Quarter-finals | 16/02/2000 | SD Compostela | - | Espanyol Barcelona | 1:0 | |
Spain