| 1. Round | 28/09/1941 | FC Barcelona | - | Hércules CF | 4:4 | ||||
| 2. Round | 05/10/1941 | Hércules CF | - | Deportivo La Coruña | 4:2 | ||||
| 3. Round | 12/10/1941 | Sevilla FC | - | Hércules CF | 7:2 | ||||
| 4. Round | 19/10/1941 | Hércules CF | - | Real Oviedo | 4:1 | ||||
| 5. Round | 26/10/1941 | CD Castellón | - | Hércules CF | 4:0 | ||||
| 6. Round | 02/11/1941 | Hércules CF | - | Atlético Aviación | 2:2 | ||||
| 7. Round | 09/11/1941 | Hércules CF | - | Espanyol Barcelona | 1:1 | ||||
| 8. Round | 16/11/1941 | RC Celta | - | Hércules CF | 4:1 | ||||
| 9. Round | 23/11/1941 | Hércules CF | - | Real Madrid | 1:2 | ||||
| 10. Round | 30/11/1941 | Valencia CF | - | Hércules CF | 7:1 | ||||
| 11. Round | 07/12/1941 | Hércules CF | - | Real Sociedad | 3:1 | ||||
| 12. Round | 14/12/1941 | Granada CF | - | Hércules CF | 7:2 | ||||
| 13. Round | 21/12/1941 | Hércules CF | - | Athletic Club | 3:1 | ||||
| 14. Round | 04/01/1942 | Hércules CF | - | FC Barcelona | 3:1 | ||||
| 19. Round | 08/02/1942 | Atlético Aviación | - | Hércules CF | 5:1 | ||||
| 20. Round | 15/02/1942 | Espanyol Barcelona | - | Hércules CF | 2:0 | ||||
| 26. Round | 05/04/1942 | Athletic Club | - | Hércules CF | 2:2 |
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