| 9. Round | 30/10/1993 | Athletic Club | - | Real Valladolid | 3:0 | ||||
| 10. Round | 06/11/1993 | RC Celta | - | Athletic Club | 1:1 |  |
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| 11. Round | 09/11/1993 | Athletic Club | - | Deportivo La Coruña | 3:1 | ||||
| 15. Round | 11/12/1993 | Athletic Club | - | Atlético Madrid | 3:2 | ||||
| 18. Round | 08/01/1994 | Athletic Club | - | Real Sociedad | 0:0 | ||||
| 20. Round | 22/01/1994 | Albacete | - | Athletic Club | 1:0 | |
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| 21. Round | 29/01/1994 | Athletic Club | - | UE Lleida | 4:0 | ||||
| 23. Round | 12/02/1994 | Athletic Club | - | Rayo Vallecano | 0:0 | ||||
| 24. Round | 19/02/1994 | Real Zaragoza | - | Athletic Club | 1:0 | ||||
| 25. Round | 22/02/1994 | Athletic Club | - | CD Logroñés | 0:0 | |
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| 27. Round | 04/03/1994 | Athletic Club | - | Valencia CF | 2:1 | ||||
| 28. Round | 12/03/1994 | Real Valladolid | - | Athletic Club | 1:1 | |
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| 30. Round | 26/03/1994 | Deportivo La Coruña | - | Athletic Club | 4:1 | |
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| 31. Round | 02/04/1994 | Athletic Club | - | Sporting Gijón | 7:0 | ||||
| 32. Round | 05/04/1994 | Real Oviedo | - | Athletic Club | 3:0 | ||||
| 36. Round | 30/04/1994 | Racing Santander | - | Athletic Club | 2:2 | ||||
| 37. Round | 07/05/1994 | Real Sociedad | - | Athletic Club | 0:0 | ||||
| 38. Round | 13/05/1994 | Athletic Club | - | CD Tenerife | 3:2 | |
Spain