| 6. Round | 18/10/1981 | CD Castellón | - | Real Sociedad | 1:3 | ||||
| 7. Round | 25/10/1981 | Atlético Madrid | - | CD Castellón | 3:0 | ||||
| 8. Round | 31/10/1981 | CD Castellón | - | Sevilla FC | 0:3 | ||||
| 9. Round | 07/11/1981 | Hércules CF | - | CD Castellón | 2:2 |  |
|||
| 10. Round | 10/11/1981 | CD Castellón | - | Real Zaragoza | 2:1 | ||||
| 12. Round | 21/11/1981 | CD Castellón | - | Espanyol Barcelona | 1:4 | |
|||
| 14. Round | 05/12/1981 | CD Castellón | - | Athletic Club | 1:2 | ||||
| 15. Round | 12/12/1981 | Real Madrid | - | CD Castellón | 4:0 | ||||
| 16. Round | 18/12/1981 | CD Castellón | - | Real Betis | 0:0 | ||||
| 23. Round | 06/02/1982 | Real Sociedad | - | CD Castellón | 3:1 | ||||
| 24. Round | 13/02/1982 | CD Castellón | - | Atlético Madrid | 3:0 | ||||
| 25. Round | 20/02/1982 | Sevilla FC | - | CD Castellón | 4:0 | ||||
| 27. Round | 06/03/1982 | Real Zaragoza | - | CD Castellón | 3:2 | ||||
| 29. Round | 20/03/1982 | Espanyol Barcelona | - | CD Castellón | 3:2 | ||||
| 30. Round | 27/03/1982 | CD Castellón | - | CA Osasuna | 1:1 | ||||
| 31. Round | 03/04/1982 | Athletic Club | - | CD Castellón | 2:1 |
Spain