| 1. Round | 01/12/1999 | CD Leganés | - | Villarreal CF | 0:3 aet |  |
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| 2. Round | 11/01/2000 | Villarreal CF | - | Barakaldo CF | 1:0 | ||||
| Round of 16 | 01/02/2000 | Villarreal CF | - | SD Compostela | 2:4 pso |  |
| 1. Round | 01/12/1999 | CD Leganés | - | Villarreal CF | 0:3 aet | |
|||
| 2. Round | 11/01/2000 | Villarreal CF | - | Barakaldo CF | 1:0 | ||||
| Round of 16 | 01/02/2000 | Villarreal CF | - | SD Compostela | 2:4 pso | |
| Moisés García León | |
| Born: | 10.07.1971 |
| Place of birth: |
Sevilla, 
Spain |
| Nationality: |
Spain
|
| Height: | 185 cm |
| Weight: | 84 kg |
| Position(s): | Centre Forward |
| Foot: | left |