| 1. Round | 06/08/2005 | RSC Anderlecht | - | RAA La Louviére | 6:0 | ||||
| 3. Round | 20/08/2005 | RSC Anderlecht | - | Germinal Beerschot | 3:1 |  |
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| 4. Round | 28/08/2005 | KRC Genk | - | RSC Anderlecht | 3:3 |  |
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| 5. Round | 10/09/2005 | RSC Anderlecht | - | Excelsior Mouscron | 3:1 | |
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| 6. Round | 17/09/2005 | FC Brussels | - | RSC Anderlecht | 1:1 | ||||
| 7. Round | 21/09/2005 | RSC Anderlecht | - | KSV Roeselare | 5:1 | |
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| 9. Round | 01/10/2005 | RSC Anderlecht | - | Sint-Truidense VV | 3:0 | |
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| 10. Round | 15/10/2005 | KSK Beveren | - | RSC Anderlecht | 0:1 | |
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| 11. Round | 23/10/2005 | RSC Anderlecht | - | Club Brugge KV | 2:2 | |
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| 13. Round | 05/11/2005 | RSC Anderlecht | - | Sporting Charleroi | 3:1 | ||||
| 14. Round | 20/11/2005 | KVC Westerlo | - | RSC Anderlecht | 2:1 | ||||
| 16. Round | 02/12/2005 | RSC Anderlecht | - | KAA Gent | 3:0 | |
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| 15. Round | 14/12/2005 | Standard Liège | - | RSC Anderlecht | 2:0 |
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