| 1. Round | 03/10/2020 | Athletic Club [Women] | - | Deportivo La Coruña [Women] | 2:1 |  |
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| 2. Round | 11/10/2020 | Sevilla FC [Women] | - | Athletic Club [Women] | 0:2 | ||||
| 3. Round | 18/10/2020 | Athletic Club [Women] | - | Real Betis [Women] | 2:2 | ||||
| 4. Round | 31/10/2020 | Valencia CF [Women] | - | Athletic Club [Women] | 1:1 | ||||
| 10. Round | 05/12/2020 | Athletic Club [Women] | - | Atlético Madrid [Women] | 3:3 | ||||
| 13. Round | 22/12/2020 | EDF Logroño [Women] | - | Athletic Club [Women] | 3:0 | ||||
| 14. Round | 06/01/2021 | Real Sociedad [Women] | - | Athletic Club [Women] | 1:0 | ||||
| 19. Round | 07/02/2021 | Athletic Club [Women] | - | Espanyol Barcelona [Women] | 3:0 | ||||
| 34. Round | 27/06/2021 | Deportivo La Coruña [Women] | - | Athletic Club [Women] | 3:0 |
Spain