| 7. Round | 04/11/1945 | Hércules CF | - | Valencia CF | 2:1 |  |
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| 8. Round | 18/11/1945 | Real Murcia | - | Hércules CF | 1:1 | ||||
| 9. Round | 25/11/1945 | Hércules CF | - | Real Oviedo | 0:3 | ||||
| 11. Round | 09/12/1945 | Real Madrid | - | Hércules CF | 2:0 | ||||
| 12. Round | 16/12/1945 | Hércules CF | - | RC Celta | 1:4 | ||||
| 13. Round | 30/12/1945 | CD Castellón | - | Hércules CF | 2:1 | |
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| 14. Round | 06/01/1946 | Sevilla FC | - | Hércules CF | 2:1 | ||||
| 16. Round | 20/01/1946 | Espanyol Barcelona | - | Hércules CF | 5:2 | ||||
| 17. Round | 27/01/1946 | Hércules CF | - | CD Alcoyano | 1:0 | ||||
| 19. Round | 10/02/1946 | Hércules CF | - | Athletic Club | 0:0 |
Spain