| 4. Round | 31/10/2020 | Valencia CF [Women] | - | Athletic Club [Women] | 1:1 | ||||
| 5. Round | 04/11/2020 | EDF Logroño [Women] | - | Valencia CF [Women] | 2:2 | ||||
| 10. Round | 05/12/2020 | Madrid CFF [Women] | - | Valencia CF [Women] | 4:1 | ||||
| 13. Round | 22/12/2020 | Valencia CF [Women] | - | SD Eibar [Women] | 4:2 | ||||
| 20. Round | 10/02/2021 | Valencia CF [Women] | - | EDF Logroño [Women] | 3:2 | ||||
| 15. Round | 14/02/2021 | Atlético Madrid [Women] | - | Valencia CF [Women] | 4:1 | ||||
| 18. Round | 27/02/2021 | Valencia CF [Women] | - | UDG Tenerife Sur [Women] | 2:2 | ||||
| 29. Round | 09/05/2021 | Santa Teresa CD [Women] | - | Valencia CF [Women] | 0:1 | ||||
| 31. Round | 22/05/2021 | SD Eibar [Women] | - | Valencia CF [Women] | 0:1 | ||||
| 32. Round | 06/06/2021 | Valencia CF [Women] | - | Sporting de Huelva [Women] | 3:1 | ||||
| 33. Round | 20/06/2021 | Levante UD [Women] | - | Valencia CF [Women] | 1:1 | ||||
| 34. Round | 27/06/2021 | Valencia CF [Women] | - | Real Sociedad [Women] | 1:3 |
Spain