| 2. Round | 18/09/2022 | Athletic Club [Women] | - | Sporting de Huelva [Women] | 3:0 | ||||
| 3. Round | 25/09/2022 | Levante UD [Women] | - | Athletic Club [Women] | 2:0 | ||||
| 5. Round | 15/10/2022 | Athletic Club [Women] | - | FC Barcelona [Women] | 0:3 | ||||
| 6. Round | 22/10/2022 | CD Alavés [Women] | - | Athletic Club [Women] | 1:1 |  |
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| 7. Round | 29/10/2022 | Athletic Club [Women] | - | Atlético Madrid [Women] | 1:4 | ||||
| 1. Round | 01/11/2022 | UDG Tenerife Sur [Women] | - | Athletic Club [Women] | 0:2 | |
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| 8. Round | 05/11/2022 | Valencia CF [Women] | - | Athletic Club [Women] | 1:2 | ||||
| 20. Round | 04/03/2023 | Sporting de Huelva [Women] | - | Athletic Club [Women] | 2:3 | ||||
| 21. Round | 12/03/2023 | Athletic Club [Women] | - | Valencia CF [Women] | 0:2 | ||||
| 22. Round | 18/03/2023 | Madrid CFF [Women] | - | Athletic Club [Women] | 3:2 | |
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| 23. Round | 24/03/2023 | Athletic Club [Women] | - | Sevilla FC [Women] | 1:1 | ||||
| 24. Round | 02/04/2023 | Real Sociedad [Women] | - | Athletic Club [Women] | 1:1 | ||||
| 25. Round | 15/04/2023 | Athletic Club [Women] | - | CD Alavés [Women] | 1:0 | |
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| 30. Round | 20/05/2023 | Athletic Club [Women] | - | Villarreal CF [Women] | 1:1 | |
Spain