1. Round 01/09/1990 Real Valladolid - CA Osasuna 1:1 yellow card
2. Round 08/09/1990 Sporting Gijón - Real Valladolid 4:0
3. Round 14/09/1990 Real Valladolid - Atlético Madrid 0:0
4. Round 22/09/1990 FC Barcelona - Real Valladolid 1:0
5. Round 29/09/1990 Real Valladolid - CD Castellón 0:0 yellow card
6. Round 07/10/1990 Sevilla FC - Real Valladolid 1:0
7. Round 14/10/1990 Real Valladolid - RCD Mallorca 5:1
8. Round 21/10/1990 Real Zaragoza - Real Valladolid 2:2
9. Round 28/10/1990 Real Valladolid - Cádiz CF 0:0 yellow card
11. Round 17/11/1990 Real Valladolid - CD Logroñés 0:0
13. Round 30/11/1990 Real Valladolid - Real Madrid 0:1 yellow card
14. Round 08/12/1990 Espanyol Barcelona - Real Valladolid 2:0
15. Round 15/12/1990 Real Valladolid - Valencia CF 3:1
16. Round 29/12/1990 Real Betis - Real Valladolid 0:0
17. Round 05/01/1991 Real Burgos - Real Valladolid 0:1
18. Round 12/01/1991 Real Valladolid - CD Tenerife 6:2
19. Round 19/01/1991 Athletic Bilbao - Real Valladolid 0:1 Goal
20. Round 26/01/1991 CA Osasuna - Real Valladolid 2:1
21. Round 02/02/1991 Real Valladolid - Sporting Gijón 0:0 yellow card
22. Round 09/02/1991 Atlético Madrid - Real Valladolid 2:0
23. Round 23/02/1991 Real Valladolid - FC Barcelona 1:5 Goal yellow card
24. Round 02/03/1991 CD Castellón - Real Valladolid 4:2 yellow card
25. Round 09/03/1991 Real Valladolid - Sevilla FC 2:1
26. Round 16/03/1991 RCD Mallorca - Real Valladolid 0:0
27. Round 23/03/1991 Real Valladolid - Real Zaragoza 0:0
28. Round 30/03/1991 Cádiz CF - Real Valladolid 0:0
29. Round 06/04/1991 Real Valladolid - Real Sociedad 4:2
31. Round 20/04/1991 Real Valladolid - Real Oviedo 1:0 yellow card
32. Round 27/04/1991 Real Madrid - Real Valladolid 1:0
36. Round 25/05/1991 Real Valladolid - Real Burgos 1:0
38. Round 08/06/1991 Real Valladolid - Athletic Bilbao 1:0