| 4. Round | 31/08/2024 | FC Barcelona | - | Real Valladolid | 7:0 | ||||
| 6. Round | 22/09/2024 | Villarreal CF | - | FC Barcelona | 1:5 |  |
|||
| 7. Round | 25/09/2024 | FC Barcelona | - | Getafe CF | 1:0 | ||||
| 8. Round | 28/09/2024 | CA Osasuna | - | FC Barcelona | 4:2 | ||||
| 10. Round | 20/10/2024 | FC Barcelona | - | Sevilla FC | 5:1 | |
|||
| 14. Round | 23/11/2024 | RC Celta | - | FC Barcelona | 2:2 | ||||
| 15. Round | 30/11/2024 | FC Barcelona | - | UD Las Palmas | 1:2 | ||||
| 21. Round | 26/01/2025 | FC Barcelona | - | Valencia CF | 7:1 | ||||
| 27. Round | 27/03/2025 | FC Barcelona | - | CA Osasuna | 3:0 | ||||
| 29. Round | 30/03/2025 | FC Barcelona | - | Girona FC | 4:1 |
Spain