| 5. Round | 21/10/1945 | Hércules CF | - | Atlético Aviación | 3:2 | ||||
| 6. Round | 28/10/1945 | Athletic Club | - | Hércules CF | 6:0 | ||||
| 7. Round | 04/11/1945 | Hércules CF | - | Valencia CF | 2:1 | ||||
| 8. Round | 18/11/1945 | Real Murcia | - | Hércules CF | 1:1 | ||||
| 9. Round | 25/11/1945 | Hércules CF | - | Real Oviedo | 0:3 | ||||
| 12. Round | 16/12/1945 | Hércules CF | - | RC Celta | 1:4 |
Spain