| 5. Round | 03/10/1965 | Sevilla FC | - | Real Zaragoza | 1:1 |  |
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| 6. Round | 10/10/1965 | Elche CF | - | Sevilla FC | 1:1 | ||||
| 7. Round | 17/10/1965 | UD Las Palmas | - | Sevilla FC | 1:0 | ||||
| 9. Round | 14/11/1965 | Athletic Club | - | Sevilla FC | 1:0 | ||||
| 10. Round | 21/11/1965 | Sevilla FC | - | Real Madrid | 2:1 | |
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| 11. Round | 28/11/1965 | FC Barcelona | - | Sevilla FC | 3:0 | ||||
| 12. Round | 05/12/1965 | Sevilla FC | - | RCD Mallorca | 3:1 | |
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| 13. Round | 12/12/1965 | CE Sabadell | - | Sevilla FC | 2:2 | ||||
| 14. Round | 19/12/1965 | Sevilla FC | - | Real Betis | 1:1 | ||||
| 15. Round | 26/12/1965 | Pontevedra CF | - | Sevilla FC | 2:1 | ||||
| 16. Round | 02/01/1966 | Valencia CF | - | Sevilla FC | 0:1 | ||||
| 17. Round | 06/01/1966 | Sevilla FC | - | Córdoba CF | 2:1 | ||||
| 18. Round | 09/01/1966 | Atlético Madrid | - | Sevilla FC | 6:1 | ||||
| 19. Round | 16/01/1966 | Sevilla FC | - | Espanyol Barcelona | 0:2 | ||||
| 20. Round | 23/01/1966 | Real Zaragoza | - | Sevilla FC | 2:0 | ||||
| 21. Round | 30/01/1966 | Sevilla FC | - | Elche CF | 2:0 | ||||
| 22. Round | 06/02/1966 | Sevilla FC | - | UD Las Palmas | 0:1 | ||||
| 28. Round | 20/03/1966 | Sevilla FC | - | CE Sabadell | 2:0 | |
Spain