| 1. Round | 10/09/1950 | CD Alcoyano | - | Racing Santander | 3:3 |  |
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| 2. Round | 17/09/1950 | RC Celta | - | CD Alcoyano | 6:2 | ||||
| 3. Round | 24/09/1950 | CD Alcoyano | - | CD Málaga | 2:1 | ||||
| 4. Round | 01/10/1950 | Espanyol Barcelona | - | CD Alcoyano | 5:3 | ||||
| 5. Round | 08/10/1950 | CD Alcoyano | - | Real Sociedad | 1:4 | ||||
| 6. Round | 15/10/1950 | Real Madrid | - | CD Alcoyano | 7:0 | ||||
| 7. Round | 22/10/1950 | CD Alcoyano | - | Valencia CF | 0:2 | ||||
| 10. Round | 12/11/1950 | CD Alcoyano | - | Deportivo La Coruña | 0:1 | ||||
| 22. Round | 25/02/1951 | Valencia CF | - | CD Alcoyano | 4:1 |
Spain