| 1. Round | 05/09/1965 | Elche CF | - | Córdoba CF | 2:0 | ||||
| 2. Round | 12/09/1965 | Atlético Madrid | - | Elche CF | 3:0 | ||||
| 3. Round | 19/09/1965 | Elche CF | - | Espanyol Barcelona | 3:0 | ||||
| 4. Round | 26/09/1965 | Real Zaragoza | - | Elche CF | 6:1 | ||||
| 6. Round | 10/10/1965 | Elche CF | - | Sevilla FC | 1:1 | ||||
| 7. Round | 17/10/1965 | CD Málaga | - | Elche CF | 0:1 | ||||
| 8. Round | 31/10/1965 | Elche CF | - | Athletic Club | 0:0 | ||||
| 12. Round | 05/12/1965 | Elche CF | - | CE Sabadell | 0:0 | ||||
| 13. Round | 12/12/1965 | Real Betis | - | Elche CF | 2:1 |
Spain