| 1. Round | 15/09/1999 | AS Monaco | - | St. Johnstone FC | 3:0 | ||||
| 1. Round | 29/09/1999 | St. Johnstone FC | - | AS Monaco | 3:3 | ||||
| 2. Round | 20/10/1999 | Widzew Łódź | - | AS Monaco | 1:1 | ||||
| 3. Round | 22/11/1999 | AEK Athen | - | AS Monaco | 2:2 | ||||
| 3. Round | 08/12/1999 | AS Monaco | - | AEK Athen | 1:0 | ||||
| Round of 16 | 01/03/2000 | RCD Mallorca | - | AS Monaco | 4:1 |  |
| Rafael Márquez Álvarez | |
| Born: | 13.02.1979 |
| Place of birth: |
Zamora, Michoacán, 
Mexico |
| Nationality: |
Mexico
Spain |
| Height: | 185 cm |
| Weight: | 83 kg |
| Position(s): | Centre Back Defensive Midfielder |
| Foot: | right |
